| Player | First | Overall | Last |
| Milito (Zaragoza) | 12 | (1) | 23 | (2) | 4 | |
| Ronaldinho (Barcelona) | 10 | (4) | 21 | (6) | 4 | (1) |
| Kanouté (Sevilla) | 10 | (2) | 21 | (3) | 3 | |
| Vílla (Valencia) | 8 | (1) | 16 | (3) | 1 | (1) |
| Fernando Baiano (Celta Vigo) | 8 | (1) | 15 | (4) | 3 | (2) |
| Fernando Torres (Atlético Madrid) | 8 | (1) | 15 | (4) | 2 | (1) |
| Van Nistelrooy (Real Madrid) | 7 | | 25 | (2) | 7 | (1) |
| Tamudo (Espanyol) | 6 | (1) | 15 | (3) | 4 | (2) |
| Sinama-Pongolle (Recreativo Huelva) | 6 | (1) | 12 | (2) | 3 | (1) |
| Morientes (Valencia) | 6 | | 13 | | 3 | |
| Güiza (Getafe) | 6 | | 11 | | 2 | |
| Portillo (Gimnàstic) | 5 | (1) | 11 | (2) | 2 | |
| Forlán (Villarreal) | 5 | | 19 | (1) | 3 | |
| Luís Fabiano (Sevilla) | 4 | (1) | 10 | (2) | 3 | |
| Robert (Real Betis) | 4 | (1) | 9 | (3) | 4 | (2) |
| Eto'o (Barcelona) | 4 | | 11 | | 2 | |
| Javi Guerrero (Recreativo Huelva) | 4 | | 7 | | 1 | |
| Raúl (Real Madrid) | 4 | | 7 | | 1 | |
| Garay (Racing Santander) | 3 | (2) | 9 | (7) | 3 | (2) |
| Yeste (Athletic Bilbao) | 3 | (2) | 5 | (2) | 0 | |
| Zigic (Racing Santander) | 3 | | 11 | | 4 | |
| Soldado (Osasuna) | 3 | | 11 | | 3 | |
| Luis García (Espanyol) | 3 | | 10 | | 5 | |
| Arango (Mallorca) | 3 | | 9 | | 5 | |
| Jankovic (Mallorca) | 3 | | 9 | | 3 | |
| Riga (Levante) | 3 | | 9 | | 2 | |
| Nenê (Celta Vigo) | 3 | | 8 | (2) | 2 | |
| Edú (Real Betis) | 3 | | 8 | | 1 | |
| Sergio Ramos (Real Madrid) | 3 | | 5 | | 1 | |
| Arizmendi (Deportivo) | 3 | | 5 | | 1 | |
| Joaquín (Valencia) | 3 | | 5 | | 1 | |
Primera División 2006/07